SELECT 
  category_id, 
  parent_id 
FROM 
  cscart_categories 
WHERE 
  parent_id IN(
    22616, 22619, 22601, 22620, 22617, 22618, 
    22605, 22606, 22615
  ) 
  AND category_id != 1

Query time 0.00005

JSON explain

{
  "query_block": {
    "select_id": 1,
    "nested_loop": [
      {
        "table": {
          "table_name": "cscart_categories",
          "access_type": "range",
          "possible_keys": ["PRIMARY", "parent", "p_category_id"],
          "key": "parent",
          "key_length": "3",
          "used_key_parts": ["parent_id"],
          "rows": 18,
          "filtered": 100,
          "index_condition": "cscart_categories.parent_id in (22616,22619,22601,22620,22617,22618,22605,22606,22615)",
          "attached_condition": "cscart_categories.category_id <> 1"
        }
      }
    ]
  }
}

Result

category_id parent_id
22602 22601
22603 22601
22604 22601
22607 22606
22608 22606
22609 22606
22610 22606
22611 22606
22612 22606
22613 22606
22614 22606